An amphoteric compound is a compound that can act either as an , or as a in a chemical reaction.
A first example of water’s amphoteric character is the fact that it can self-ionize to a small extent. What that means is that a water molecule is capable of donating one of its protons (##”H”^(+)##) to a neighbouring water molecule, forming the hydroxyde and hydronium ions.
##H_2O + H_2O rightleftharpoons H_3O^(+) + OH^(-)##
One of the two water molecules acts as an and donates a proton to the other water molecule, which subsequently acts as a .
Water can act as an acid or as a base in various chemical reactions, the most common two examples involving the ammonia and hydrochloric acid reactions.
##NH_(3(aq)) + H_2O_((l)) rightleftharpoons NH_(4(aq))^(+) + OH_((aq))^(-)##
Here water acts as a Bronsted-Lowry acid because it donates a proton to ammonia.
##HCl_((g)) + H_2O((l)) rightleftharpoons H_3O_((aq))^(+) + Cl_((aq))^(-)##
This time water acts a Bronsted-Lowry base because it accepts a proton from hydrochloric acid.
To be exact, in reactions that involve the transfer of protons, the term is actually amphiprotic.
Water can act as a or as a as well; in such reactions, water can either accept a pair of electrons, which makes it a Lewis acid, or donate a pair of electrons, which makes it a Lewis base.
Here’s another example of water’s amphiprotic (amphoteric) nature:
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